usermod -d 新しいホームディレクトリ　ユーザー名

usermodその他のオプション
-a, --append append the user to the supplemental GROUPS
(use only with -G)
-c, --comment COMMENT new value of the GECOS field
-d, --home HOME_DIR new home directory for the user account
-e, --expiredate EXPIRE_DATE set account expiration date to EXPIRE_DATE
-f, --inactive INACTIVE set password inactive after expiration
to INACTIVE
-g, --gid GROUP force use GROUP as new primary group
-G, --groups GROUPS new list of supplementary GROUPS
-h, --help display this help message and exit
-l, --login NEW_LOGIN new value of the login name
-L, --lock lock the user account
-m, --move-home move contents of the home directory to the new
location (use only with -d)
-o, --non-unique allow using duplicate (non-unique) UID
-p, --password PASSWORD use encrypted password for the new password
-s, --shell SHELL new login shell for the user account
-u, --uid UID new UID for the user account
-U, --unlock unlock the user account
-Z, --selinux-user new selinux user mapping for the user account